ionic solvation

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离子溶剂化

Study of electrolyte solution has long been a challenging theme due to the intrinsic complexities involved such as the long-range interionic interaction, the ionic solvation, mixed solvents and mixed electrolytes etc.
由于电解质溶液内在的复杂性，如离子间长程作用力、离子水化作用、混合溶剂和混合电解质等等，对电解质溶液的研究一直是挑战性课题之一。
An Application of SPT in the Calculation of Ionic Solvation Free Energy of Transfer
溶剂化热力学的理论研究（Ⅱ）&定标粒子理论在离子迁移自由能计算中的应用
The Application of Scaled Particle Theory in Calculation for Free Energy of Ionic Solvation
定标粒子理论在离子溶剂化自由能计算中的应用
The transfer free energy and entropy of KCl and NaCl from pure methanol to mixed solvents were evaluated from the measurements, thus the structure property of solution, the effect of salt on it, the ionic solvation and the tendentiousness of solution were discussed preliminarily.
根据实验结果，计算得NaCl和KCl自甲醇至混合溶剂的转移自由能和熵。对离子在此混合物中的溶剂化、结构影响和盐的溶解倾向作了初步解释。